So there are some complexities to keep in-mind with this. To get the benefits of the 110 loot list you need to be fighting monsters that are in the Level 110 content.
If you go to a zone where the maximum monster level is a lot lower you'll get drops from the 'lower level' portion of his loot list. For instance if the dungeon is for levels 10 to 15 and you go there as a 110 and you get Lev'Lar to spawn, he's going to be ~level 15 when he dies. Hope this makes sense :-)
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