Depends on the map. Say you're in AO3. It is possible to drop stuff from mobs there. Even the barrels can drop pinks, as I have experimented long ago. Now let's take BSM. No pinks to my knowledge has ever dropped from a mob. So if the thing rerolled, it would still be a purple because if no pinks are "available" for you to loot, you wouldn't get a pink. But say if you got a green from BSM. You would get a purple because you can get a purple in the map you're in. Forest Manor can even drop pinks from barrels. Forest Tombs can get you pinks from killing Skeller/Meathead. So it really depends on the map.
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